Materazzi started the 2006 FIFA World Cup as a reserve player, but after Alessandro Nesta suffered an injury in the group match against the Czech Republic, Materazzi came on as his replacement and made an impact by scoring a goal, and was named Man of the Match. He received a red card in the round of 16 match against Australia for a foul on Mark Bresciano, which ended in a 1–0 win to the Italians, and was suspended for the quarter-final against Ukraine, which Italy won 3–0. In the final against France, Materazzi fouled Florent Malouda to concede a dubious penalty, which Zinedine Zidane subsequently scored. He made another impact by scoring a goal to level the score, a header from a right sided corner by Andrea Pirlo. After the match went to extra-time, Materazzi and Zidane were involved in a confrontation in the 110th minute, where Materazzi verbally insulted Zinedine Zidane alongside tugging his shirt while Zidane attempted to walk away, which ended with Zidane head-butting Materazzi and receiving a red card. The game then continued to penalties. Materazzi scored Italy’s second penalty as they defeated France 5–3 to claim their fourth FIFA World Cup. After the final, the confrontation resulted in a major controversy as Zidane accused Materazzi of insulting his sister and mother. Additionally, Materazzi claimed that after he had grabbed Zidane’s jersey, Zidane sarcastically said to him “If you want my shirt, I will give to you afterwards”. Materazzi then revealed that he replied, “Preferisco la puttana di tua sorella” (I would prefer your whore of a sister), which resulted in the head-butt. Three British tabloid newspapers, the Daily Star, the Daily Mail and The Sun, alleged that Materazzi had called Zidane “the son of a terrorist whore.” Materazzi took legal action against all three newspapers and the allegations were later withdrawn. FIFA later issued a CHF 5,000 fine and a two-match ban against Materazzi. Alongside striker Luca Toni, Materazzi was Italy’s top scorer throughout the tournament with two goals; he also won 14 challenges throughout the competition.